Blue Glow -- what causes it?
Glass tubes have visible glow inside them. Most audio types use
oxide-coated cathodes, which glow a cheery warm orange color. And
thoriated-filament tubes, such as the SV811 and SV572 triodes, show
both a white-hot glow from their filaments and (in some amplifiers) a
slight orange glow from their plates. All of these are normal effects.
Some newcomers to the tube-audio world have also noticed that some of
their tubes emit a bluish-colored glow. There are TWO causes for this
glow in audio power tubes; one of them is normal and harmless, the
other occurs only in a bad audio tube.
1) Most Svetlana glass power tubes show FLUORESCENCE GLOW. This is a
very deep blue color. It can appear wherever the electrons from the
cathode can strike a solid object. It is caused by minor impurities,
such as cobalt, in the object. The fast-moving electrons strike the
impurity molecules, excite them, and produce photons of light of a
characteristic color. This is usually observed on the interior of the
plate, on the surface of the mica spacers, or on the inside of the
glass envelope. THIS GLOW IS HARMLESS. It is normal and does not
indicate a tube failure. Enjoy it. Many people feel it improves the
appearance of the tube while in operation.
2) Occasionally a tube will develop a small leak. When air gets into
the tube, AND when the high plate voltage is applied, the air molecules
can ionize. The glow of ionized air is quite different from the
fluorescence glow above--ionized air is a strong purple color, almost
pink. This color usually appears INSIDE the plate of the tube (though
not always). It does not cling to surfaces, like fluorescence, but
appears in the spaces BETWEEN elements. A tube showing this glow should
be replaced right away, since the gas can cause the plate current to
run away and (possibly) damage the amplifier.
PLEASE NOTE: some older hi-fi and guitar amplifiers, and a very few
modern amplifiers, use special tubes that DEPEND on ionized gas for
their normal operation.
-Some amps use mercury vapor rectifiers, such as types 83, 816, 866 or
872. These tubes glow a strong blue-purple color in normal use. They
turn AC power into DC to run the other tubes.
-And occasionally, vintage and modern amplifiers use gas-discharge
regulator tubes, such as types 0A2, 0B2, 0C2, 0A3, 0B3, 0C3 or 0D3.
These tubes rely on ionized gas to control a voltage tightly, and
normally glow either blue-purple or pink when in normal operation. If
you are unsure if these special tubes are used in your amplifier,
consult with an experienced technican before replacing them.
http://www.vacuumtubes.net/How_Vacuum_Tubes_Work.htm